What are the best ways of collecting rainwater, ex-roof run off.
The Roof gets treated for Moss, which is a real problem, and the chemicals are ones I wouldn't wish in drinking / cooking water.
Discussions about procuring and purifying water
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Considering the pollutants in the atmosphere and the possible contamination from eves troughs and piping (as well as chemically treated surfaces ), I would treat, boil or adequately filter any rainwater if it was feasible to do so. This is assuming that this water was to be used for human consumption.
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